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Effect of Auxiliary Gases on Combustion Synthesis of Si3N4

Weiping SHEN , Fei WANG , Zhuohui WU , Changchun GE

材料科学技术(英)

This paper presents results of combustion synthesis (Self-Propagating High Temperature Synthesis, SHS) of Si3N4 under nitrogen with argon, hydrogen or ammonia. Higher percentages of α-Si3N4 content were obtained in large size cakes in SHS with hydrogen and ammonia than those with argon. Effect of the auxiliary gases for combustion synthesis of Si3N4 on α phase content, on phase transformation of α-Si3N4 to β-Si3N4 in SHS Si3N4 and on oxygen content in SHS Si3N4 were investigated.

关键词: Combustion synthesis , null , null , null

Combustion Synthesis of Ti-2B-Cu/Ni and 3Ti-2BN-Cu/Ni Bilayered Cermets

Weiping SHEN , Wenbin CAO , Changchun GE , E.H.Grigoryan , A.E.Sytschev , A.S.Rogachev

材料科学技术(英)

The effects of Cu and Ni (x=0, 10, 20 and 40 wt pct) and compaction pressures (12, 24, 84 and 108 MPa) on combustion wave velocity and wave front shape for Ti-2B-Cu/Ni and 3Ti-2BN-Cu/Ni bilayered cermets were investigated by a video camera. Since the boiling point of Cu is lower, the wave velocities of specimens are slower. Due to the higher specific heat of Ni than that of Cu, the wave velocities of specimens was slowed down a lot with increasing the Ni diluent. The wave velocity differences of the specimens containing Ni are more than that of the bilayered specimens containing Cu. Wave velocities of the specimens containing Ni increased more than that of the specimens containing Cu when higher pressure was employed for green mixture. The more the wave velocity difference of the bilayer, the more curved the specimen.

关键词: Combustion synthesis , null , null

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